Consider the equilibrium reaction: 3CIO-(aq) ↔ CIO3-(aq) + 2CI-(aq)The equilibrium constant Kc = 3.2 X 103. The following concentrations are present: [Cl-] = 0.50 mol/L; [ClO3-] = 0.32 mol/L; [ClO-] = 0.24 mol/L. Is the mixture at equilibrium and, if not, in which direction will reaction proceed?
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Answer: Right shift
Explanation:
We have to know the Reaction quotient Qc, and the formula for Qc is the same as Kc, but instead of measuring equilibrium, it's like a snapshot of the reaction showing where it is. Too many products? Make some more reactants. Too many reactants? Make more products. Or if the reaction is at equilibrium.
Q < Kc -> right shift
Q > Kc -> left shift
Q = Kc -> equilibrium
For this problem,
Qc = (0.5)^2*(0.32)/(0.24)^3 = 5.78
5.78 < 3.2*10^3
So we gotta make more product by right shifting the reaction.
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