conversion aldopentose to aldohexose
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The aldohexose is selectively oxidised with Br-water to convert aldehyde into carboxylic acid. ... Wohl's degradation: Here the aldohexose is converted into an oxime by reaction with hydroxylamine. This is further reacted with sod. ✔✔
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Hey Dear,
◆ Kiliani–Fischer synthesis -
- It lengthens the aldose chain by 1 CH(OH) & converting it to hexose.
- This reaction takes place through formation of cyanohydrin.
- First the aldose is treated with aq.NaCN to form cyanohydrin which is then hydrolysed to get susequent aldose.
# Reaction -
Aldopentose is first treated with aq.NaCN and then heated with water to obtain aldohexose.
Aldopentose + (NaCN/H2O) --> Aldohexose
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