Correct order of boiling point for the alkyl halide is:
(A) CH.C> C,H,Br > CHI (C) CHI>C,H,Br > CH.CH
(B) CH.I>C,H,CI>C,H, Br
(D) C,H,Br > C,H,I > CHCI
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Answer:
option A
Explanation:
For the same alkyl group, the boiling point of haloalkanes decreases in the order CI > CBr > CHl . This is due to the increase in van der Waals forces when the size and mass of the halogen atom increases. For isomeric haloalkanes, the boiling point decrease with increase in branching.
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