Covalency of chlorine atom in 2nd excited state will be
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Electronic configuration of chlorine is:
1s^2 2s^2 2p^6 3s^2 3p^5
First excited state will be: 1s^2 2s^2 2p^6 3s^1 3p^6
Second excited state will be: 1s^2 2s^2 2p^6 3s^0 3p^6 4s^1
One unpaired electron present in 4s orbital
n =4
l =0
m =0
n+l+m =4+0+0 = 4
Therefore, the maximum unpaired electrons i.e. covalency of chlorine in second excited state will be 4
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[Ne] 3s2 3p3 4s2
that is Max covalency =4
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