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Polar molecules occur when there is an electronegativity difference between the bonded atoms. Nonpolar molecules occur when electrons are shared equal between atoms of a diatomic molecule or when polar bonds in a larger molecule cancel each other out.
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When there is no disparity between the electronegativities of molecules, the bond will be nonpolar covalent bonds. On the other hand, when the more electronegative atom pulls an electron from the other atom, then polar .
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