Dage
glass transition temp in PMMA
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Figure 2 shows the DSC heating traces of bulk PMMA6K and PMMA6K confined in 80 nm AAO nanopores. The bulk PMMA6K exhibits a single Tg at about 110 °C (denoted as Tg,bulk), while the glass transition behavior of PMMA6K confined in the AAO nanopores deviates dramatically from the bulk characteristics.
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