decreasing order of +I effect
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Relative inductive effects have been experimentally measured with reference to hydrogen, in increasing order of −I effect or decreasing order of +I effect, as follows: –NH3+ > –NO2 > –SO2R > –CN > –SO3H > –CHO > –CO > –COOH > –COCl > -CONH2 >-F > –Cl > –Br > –I > –OR > -OH > -NR2 > –NH2 > –C6H5 > –CH=CH2 > –H.
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The decreasing order of -I effect is
I.R
4
N
⊕
>II.NO
2
>III.CN>IV.SO
3
H>V.COOH
As the magnitude of the positive charge on an atom decreases, the -I effect decreases.
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