Chemistry, asked by rajanikantadoley709, 3 months ago

Deduce the reduced equation of states from van der Waals' equation of states and define the law of corresponding
states from it. ​

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Answered by sartajtareen00
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Answered by minasharmaminaedu
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Reduced equation of states from van der Waals' equation : (p+ a/V) (V- b) = nRT

The law of corresponding states:

"This law can be defined as the equations of states for real gases are similar when these gases are expressed in reduced temperature, pressures, and volumes at critical point."

Explanation:

According to van der Waals gas theory, the theorem of corresponding states defines that all the gases and liquids are when compared at the same reduced temperature and reduced pressure, they have approximately the same compressibility factor and all deviate from ideal gas behavior at same parameters.

So by adding certain terms to the ideal gas equation we can define the parameters for real gas also and that deducted equation is termed as reduced equation of states.

Mathematical form:

(p+ a/V) (V- b) = nRT

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