Define catenation. Please explain it in detail too.
Answers
Catenation is the linkage of atoms of the same element into longer chains. Catenation occurs most readily in carbon, which forms covalent bonds with other carbon atoms to form longer chains and structures. This is the reason for the presence of the vast number of organic compounds in nature. Carbon is most well known for its properties of catenation, with organic chemistry essentially being the study of catenated carbon structures (and known as catenae). However, carbon is by no means the only element capable of forming such catenae, and several other main group elements are capable of forming an expansive range of catenae, including silicon, sulfur and boron.
The ability of an element to catenate is primarily based on the bond energy of the element to itself, which decreases with more diffuse orbitals (those with higher azimuthal quantum number) overlapping to form the bond. Hence, carbon, with the least diffuse valence shell p orbital is capable of forming longer p-p sigma bonded chains of atoms than heavier elements which bond via higher valence shell orbitals. Catenation ability is also influenced by a range of steric and electronic factors, including the electronegativity of the element in question, the molecular orbital hybridization and the ability to form different kinds of covalent bonds. For carbon, the sigma overlap between adjacent atoms is sufficiently strong that perfectly stable chains can be formed. With other elements this was once thought to be extremely difficult in spite of plenty of evidence to the contrary.
The versatile chemistry of elemental sulfur is largely due to catenation. In the native state, sulfur exists as S8 molecules. On heating these rings open and link together giving rise to increasingly long chains, as evidenced by the progressive increase in viscosity as the chains lengthen. Selenium and tellurium also show variants of these structural motifs.
Silicon can form sigma bonds to other silicon atoms (and disilane is the parent of this class of compounds). However, it is difficult to prepare and isolate SinH2n+2 (analogous to the saturated alkane hydrocarbons) with n greater than about 8, as their thermal stability decreases with increases in the number of silicon atoms. Silanes higher in molecular weight than disilane decompose to polymeric polysilicon hydride and hydrogen.[1][2] But with a suitable pair of organic substituents in place of hydrogen on each silicon it is possible to prepare polysilanes (sometimes, erroneously called polysilenes) that are analogues of alkanes. These long chain compounds have surprising electronic properties - high electrical conductivity, for example - arising from sigma delocalization of the electrons in the chain.[3]
Phosphorus chains (with organic substituents) have been prepared, although these tend to be quite fragile. Small rings or clusters are more common.
Even silicon–silicon pi bonds are possible. However, these bonds are less stable than the carbon analogues. Disilane is quite reactive compared to ethane. Disilylenes are quite rare, unlike alkenes. Examples of disilynes, long thought to be too unstable to be isolated[4] were reported in 2004.[5]
In recent years a variety of double and triple bonds between the semi-metallic elements have been reported, including silicon, germanium, arsenic, bismuth and so on. The ability of certain main group elements to catenate is currently the subject of research into inorganic polymers.
The property of element due to which it forms covalent bonds with other atoms of the same element to form a chain of atoms is called catenation.
Carbon has a unique nature in that it is able to catenate and form millions of organic compounds. Carbon shows the property of catenation to the maximum extent. Apart from carbon sulphur, silicon etc also show this property to some extent.
Carbon may form bonds with other atoms of carbon. This carbon property is known as catenation, carbon can form a long chain due to catenation; thus bonding with other carbon atoms. By catenation, carbon can produce single, double and triple bonds.
Examples are sulphur show catenation up to eight atoms in the formation of S8 molecules of sulphur. It also shows catenation in polysulphide ions Sn2-, Sulphanes H-Sn-H and polysulfuric acid HO2S-Sn-SO3H.