define diasteriotopic and enantiotopic
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Diasteriotopic: In stereochemistry, topicity is the stereochemical relationship between substituents and the structure to which they are attached. Depending on the relationship, such groups can be heterotopic, homotopic, enantiotopic, or diastereotopic.
Enantiotopic:The stereochemical term enantiotopic refers to the relationship between two groups in a molecule which, if one or the other were replaced, would generate a chiral compound. The two possible compounds resulting from that replacement would be enantiomers..
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Diasteriotopic: In stereochemistry, topicity is the stereochemical relationship between substituents and the structure to which they are attached. Depending on the relationship, such groups can be heterotopic, homotopic, enantiotopic, or diastereotopic.
Enantiotopic:The stereochemical term enantiotopic refers to the relationship between two groups in a molecule which, if one or the other were replaced, would generate a chiral compound. The two possible compounds resulting from that replacement would be enantiomers..
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When you have two hydrogens attached to a single carbon, they can have three different types of relationships. We call them “homotopic”, “enantiotopic”, and “diastereotopic”. ... For example, free radical chlorination replaces C-H bonds with C-Cl bonds.
Constitutionally equivalent atoms or groups of a molecule which are not symmetry related.
Replacement of one of twodiastereotopic atoms or groups results in the formation of one of a pair of diastereoisomers.
In the example below the two hydrogen atoms of the methylene group C-3 arediastereotopic. See also prochirality; enantiotopic; heterotopic.
Constitutionally equivalent atoms or groups of a molecule which are not symmetry related.
Replacement of one of twodiastereotopic atoms or groups results in the formation of one of a pair of diastereoisomers.
In the example below the two hydrogen atoms of the methylene group C-3 arediastereotopic. See also prochirality; enantiotopic; heterotopic.
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