Define internal energy of a system. Is it a state variable or not? What is the nature of the internal energy of an ideal gas?
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Internal Energy and the State of a System
The state of a system refers to the quintessential
properties fully define a system’s characteristics.
Internal energy U is part of the description of the state
of a system – the energy it has by just sitting there, not
macroscopically moving. Its main constituents are:
C Random motions of atomic particles (temperature)
C Interatomic and intermolecular potential energies
State variables are the quantities that specify the essential
internal state of a system:
C Temperature
C Pressure
C Volume
C Phase or internal structure (gaseous, crystalline, etc.)
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