define molecular orbital theory
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In molecular orbital theory, electrons in a molecule are not assigned to individual chemical bonds between atoms, but are treated as moving under the influence of the atomic nuclei in the whole molecule.
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Molecular Orbital Theory (often abbreviated to MOT) is a theory on chemical bonding developed at the beginning of the twentieth century by F. Hund and R. S. Mulliken to describe the structure and properties of different molecules. The valence-bond theory failed to adequately explain how certain molecules contain two or more equivalent bonds whose bond orders lie between that of a single bond and that of a double bond, such as the bonds in resonance-stabilized molecules. This is where the molecular orbital theory proved to be more powerful than the valence-bond theory (since the orbitals described by the MOT reflect the geometries of the molecules to which it is applied).
shahul86:
1)The atomic orbitals overlap to form new orbitals called molecular orbitals. When two atomic orbitals overlap or combine ,they lose their identity and form new orbitals. The new orbitals thus formed are called molecular
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