define specific reaction rate constant and its SI unit
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The specific rate constant (k) is the proportionality constant relating the rate of the reaction to the concentrations of reactants.
It depends on the order of the reaction.
Zero Order Reactions
rate = k[A]0
M/t = k
k units: M/s, M/min, M/hr, etc.
First Order Reactions
rate = k[A]
M/t = k M
k units: s-1, min-1, hr-1, etc.
Second Order Reactions
rate = k[A]2 rate = k[A][B]
M/t = k M2
k units: M-1s-1, M-1min-1, M-1hr-1, etc.
Third Order Reactions
rate = k[A]3 rate = k[A]2[B] rate = k[A][B][C]
M/t = k M3
k units: M-2s-1, M-2min-1, M-2hr-1, etc.
n Order Reactions
rate = k[A]n
M/t = k Mn
k units: M-(n-1)s-1, etc.
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