definition of drying agent and briefly explain about ir
Answers
Drying agents (also called desiccants) come in various forms and have found widespread use in the foods, pharmaceuticals, packing, electronics and many manufacturing industries. A desiccant is a hygroscopic substance that induces or sustains a state of dryness in its vicinity. Ideally, it is chemically stable and chemically inert (i.e., silica). Unfortunately, this is not always the case in the chemistry lab because the drying agent comes into direct contact with the solvent and the chemical.
Many organic solvents are immiscible with aqueous solutions, but they are able to dissolve significant amounts of water because of their polarity i.e., diethyl ether dissolves 7 % of its weight in water while tetrahydrofuran is completely miscible with water (Why?). Unfortunately, water is a compound that is very difficult to remove from many compounds, because they are either holding on to it well (i.e., alcohols) or the compound itself is steam volatile. Bottom-line is that the more polar the solvent is, the more hygroscopic it will usually be because it dissolves the water better. Thus, removing water and other impurities from a solution can become an arduous task but is necessary if the reagents are also sensitive towards water i.e., Grignard reagents or in cases where water has a detrimental effect on the yield or rate of the reaction. In those cases, drying agents like calcium hydride (CaH2), sodium metal (in combination with benzophenone) or lithium aluminum hydride (LiAlH4) are used to chemically destroy the water in the solvent. Those compounds are relatively reactive and difficult to handle and usually not used in lower division undergraduate laboratories