Derivation of gibbs-duhem-margules equation using gibbs-duhem equation?
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Duhem - Margulus equation give the relation between change of mole fraction with partial pressure of a component in a liquid mixture. ... μ = μo + RT In P , where P is partial pressure of component.
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In thermodynamics, the Gibbs Duhem Equation describes the relationship between changes in chemical potential and includes components in thermodynamics systems.
It includes necessary relationship so that equations have been carried out by small thermodynamics ranges.
Use the relation to show that, when the fugacities are replaced by pressures, if Raoult's law applies to one component in a mixture then Henry's law must apply to the other.
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