Derive an expression for pressure on ideal gas ?
Answers
If we combine the results of all the above gas laws we get an equation that holds true for an ideal gas. The most common form of this equation is since PV= K and V/T =k then
PV/T = constant
Thus, the Ideal Gas Equation is given as
where,
P= pressure of the gas
V=volume of the gas
n= Number of Moles
T=Absolute temperature
R=Ideal Gas constant also known as Boltzmann Constant = 0.082057 L atm K-1 mol-1.
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PhysicsPressurePressure Of Ideal Gas
Calculating Pressure Of An Ideal Gas
Imagine an ideal gas contained in a container which is cubical in shape. Let one corner of the cube be the origin O, and let the x, y, z-axes along the edges. Let A1and A2 be the parallel faces perpendicular to the x-axis. Consider a molecule moving with velocity v in the container. The components of velocity along the axes are vx, vy, and vz. Now, when the molecule is colliding with face A1, the x component of velocity is reversed while the y and z component of velocity remains unchanged (as per our assumption that the collisions are elastic).
The change in momentum of the molecule is:
ΔP = (−mvx)–(mvx) = −2mvx ……….. (1)
Since the momentum remains conserved, the change in momentum of the wall is 2mvx
After the collision, the molecule travels towards the face A2 with x component of the velocity equal to −vx.
Distance traveled from A1 to A2 = L
Therefore time = Lvx
After collision with A2, the molecule again travels to A1. Thus the time between two collisions is 2Lvx
Therefore the number of collisions of the molecule per unit time:
n = vx2L ………………… (2)
Using equations 1 and 2,
The momentum imparted per unit time to the wall by the molecule:
ΔF = nΔp
= mLv2x
Therefore, total force on the wall A1 due to all the molecules is
F = ƩmLvx2
= mLƩvx2
Now, Ʃvx2 = Ʃvy2 = Ʃvz2 (symmetry)
= 13Ʃv2
Therefore, F = 13mLƩv2
Pressure is force per unit area so that
P = FL2
= 13ML3∑v2N
= 13ρ∑v2N
Where
M= total mass of gas
ρ = density of the gas
Now, ∑v2N is written as v2 and is called the mean square speed.
P= 13ρv2