Derive the following:
1) Normality = (%age x density x 10) / Equivalent mass of solute
2) Relation between molarity and molality when density and molar mass of the solute is given.
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Vikrant Gupta asked in Chemistry
Derive a relation among molarity,molality,density gm/litre and molar mass of solute.
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Kanika answered this
1916 helpful votes in Chemistry, Class XII-Science
Let us take M = Molarity of solution
V = Volume of solution in L
ρ = density of solution
na and nb be the number of moles of solvent and solute, respectively.
Ma and Mb be the molar masses of solvent and solute, respectively.
Wa = weight of solvent, Wb = weight of solute

On substituting equation (1) in equation (2), we get

On Substituting equation (4) and equation (5) in equation (3), we get

On rearranging equation (6), we get

Substitute equation (7) in equation (I)

Taking V in common, we get,

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