derive the relation between molar mass, density of substance and unit cell edge length of crystal
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The relation between molar mass, the density of a substance, and unit cell edge length of crystal are derived below-
- Density is the mass per unit volume. density (d) = mass / volume
density = mass of unit cell/volume of the unit cell
- Mass of unit cell = (Z×M) / N₀
Where Z is the effective number of atoms in the unit cell, m is molar mass, and N₀ is the Avogadro number
- Therefore, d = (Z×M)/(N₀×a³)
where a is the edge length of the unit cell.
- Therefore, density = (Z×M)/(N₀×a³)
So density is directly proportional to the molar mass of the unit cell and inversely proportional to the cube of the unit cell edge length of the crystal.
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