Chemistry, asked by nandeshwardevyani23, 6 months ago

derive the relation between molar mass, density of substance and unit cell edge length of crystal​

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Answered by anjichandan14
17

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Answered by amikkr
31

The relation between molar mass, the density of a substance, and unit cell edge length of crystal are derived below-

  • Density is the mass per unit volume. density (d) = mass / volume

        density = mass of unit cell/volume of the unit cell

  • Mass of unit cell = (Z×M) / N₀

       Where Z is the effective number of atoms in the unit cell, m is molar mass, and N₀ is the Avogadro number

  • Therefore, d = (Z×M)/(N₀×a³)

        where a is the edge length of the unit cell.

  • Therefore, density = (Z×M)/(N₀×a³)

So density is directly proportional to the molar mass of the unit cell and inversely proportional to the cube of the unit cell edge length of the crystal.

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