Derive thermodynamically kirchhoff equation
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Kirchhoff's Law describes the enthalpy of a reaction's variation with temperature changes. In general, enthalpy of any substance increases with temperature, which means both the products and the reactants' enthalpies increase. The overall enthalpy of the reaction will change if the increase in the enthalpy of products and reactants is different.
HTf=HTi+cp(Tf−Ti)is the formula
where,
cpcp is the (assumed constant) heat capacity andHTiHTi and HTfHTf are the enthalpy at the respective temperatures.
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