describe in brief the hydrides of nitrogen.
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NH3, N2H4, N2H2 NH3 only thermally stable hydride. Prepared industrially by the Haber process (500 oC, high pressure),naturally by nitrogen fixation. Uses of Ammonia 4NH3 + 5O4NO + 4H2O (Huge scale) NH3 + NaOCl NH2Cl + NaOH Chloramine NH3 + NH2Cl N2H4 + NaCl + H2O (Raschig process) Side reaction 2NH2Cl + N2H4 N2 + NH4Cl catalysed by traces (ppm) of metal ions, add gelatin. Structure Acid/Base properties NH3 basic N2H4, weakly basic NH4+ N2H5+, N2H62+ Redox properties Both NH3 and N2H4 mild reducing agent (ox states -3 and -2). Reactions complex in aq solution Summary of reactivity
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NH3, N2H4, N2H2 NH3 only thermally stable hydride. Prepared industrially by the Haber process (500 oC, high pressure),naturally by nitrogen fixation. Uses of Ammonia 4NH3 + 5O4NO + 4H2O (Huge scale) NH3 + NaOCl NH2Cl + NaOH Chloramine NH3 + NH2Cl N2H4 + NaCl + H2O (Raschig process) Side reaction 2NH2Cl + N2H4 N2 + NH4Cl catalysed by traces (ppm) of metal ions, add gelatin. Structure Acid/Base properties NH3 basic N2H4, weakly basic NH4+ N2H5+, N2H62+ Redox properties Both NH3 and N2H4 mild reducing agent (ox states -3 and -2). Reactions complex in aq solution Summary of reactivity
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