Describe the basic principle of pH metric titration.
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The principles that pH-metric titration works on are-
- pH can be defined as the negative logarithm of H ion activity.
pH = -log [H+]
- Initial pH is dependent on the initial concentration of strong acid. As the strong base is added the pH increases slowly.
- The pH of the solution before the equivalence point increases quickly.
- Athe the point of equivalence the number of moles of acid is equal to the number of moles of base stoichiometrically.
- The pH after the equivalent point is determined by the concentration of excess NaOH.
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