Question

describe the ligand substitution reactions of octahedral complexes​

Answer 1

here is answer

In the context of molecular orbital theory, two potential mechanisms are discussed for replacement responses in octahedral complexes, ML6. Jorgensen's model is used to calculate the change in activation energy on the type of ML5 (D3h symmetry), ML5 (C4vsymmetry, and ML7 D5h symmetry) with angular parameters. Analysis of the received quantities (Table 4) indicates that low spin complexes with high spin mL 6 octahedral complexes, and D6 electronic configurations of metals with D3 or D8 electronic configuration are particularly stable. An SN1 system , Apparently, is the specialty for the complexes of metals with D1D2 electronic configuration. The formation bond formation facilitates the course of replacement responses in octahedral campuses. The results we have achieved explain the available experimental materials and allow us to make some predictions.