Describe the molecular structure of Blue Vitriol with the help of picture.
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• Cupric sulfate is a salt formed by treating cupric oxide with sulfuric acid. It forms as large, bright blue crystals containing five molecules of water (CuSO4∙5H2O) and is known in commerce as blue vitriol.
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Blue Vitriol is Penta hydrated copper sulphate. On heating at 100
o
C it loses 4 molecules of crystallization. At 230
o
C, it loses 5
th
molecules of water and becomes white amorphous powder. The powder again becomes blue in presence of water. It undergo dissociation on strong heating.
CuSO
4
5H
2
O
100
o
C
CuSO
4
.H
2
O+4H
2
O
Pentahydrated Monohydrated
copper sulphate copper sulphate
CuSO
4
.H
2
O
230
o
C
CuSO
4
+H
2
O
Anhydrous copper
sulphate
CuSO
4
730
o
C
CuO+SO
3
Explanation:
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