Describe the synthetic application of aluminium chloride
Answers
2 Al + 3 Cl2 → 2 AlCl32 Al + 6 HCl → 2 AlCl3 + 3 H2
Aluminum chloride may be formed via a single displacement reaction between copper chloride and aluminum metal.
2 Al + 3 CuCl2 → 2 AlCl3 + 3 Cu
In the US in 1993, approximately 21,000 tons were produced, not counting the amounts consumed in the production of aluminium.
Hydrated aluminium trichloride is prepared by dissolving aluminium oxides in hydrochloric acid. Metallic aluminum also readily dissolves in hydrochloric acid ─ releasing hydrogen gas and generating considerable heat. Heating this solid does not produce anhydrous aluminium trichloride, the hexahydrate decomposes to aluminium hydroxide when heated:
Al(H2O)6Cl3 → Al(OH)3 + 3 HCl + 3 H2O
Aluminium also forms a lower chloride, aluminium(I) chloride (AlCl), but this is very unstable and only known in the vapour phase.
Aluminium chloride is manufactured on a large scale by the exothermic reaction of aluminium metal with chlorine or hydrogen chloride at temperatures between 650 to 750 °C (1,202 to 1,382 °F).
2 Al + 3 Cl2 → 2 AlCl32 Al + 6 HCl → 2 AlCl3 + 3 H2
Aluminum chloride may be formed via a single displacement reaction between copper chloride and aluminum metal.
2 Al + 3 CuCl2 → 2 AlCl3 + 3 Cu
In the US in 1993, approximately 21,000 tons were produced, not counting the amounts consumed in the production of aluminium.
Hydrated aluminium trichloride is prepared by dissolving aluminium oxides in hydrochloric acid. Metallic aluminum also readily dissolves in hydrochloric acid ─ releasing hydrogen gas and generating considerable heat. Heating this solid does not produce anhydrous aluminium trichloride, the hexahydrate decomposes to aluminium hydroxide when heated:
Al(H2O)6Cl3 → Al(OH)3 + 3 HCl + 3 H2O
Aluminium also forms a lower chloride, aluminium(I) chloride (AlCl), but this is very unstable and only known in the vapour phase.