Chemistry, asked by arifshaikhas90, 1 year ago

Designate the value of n and i for 3d subshell

Answers

Answered by kallurisubhashini435
0

The important thing to realize here is that there's nothing special about the 3d-subshell in terms of the number of orbitals it contains.

The d-subshell contains five orbitals regardless of the energy level on which the subshell is located - as long as  

n ≥ 3 .

Each subshell is characterized by a distinct value of the angular momentum quantum number,  l

The number of orbitals each subshell can hold is determined by the magnetic quantum number,  m

The relationshop between the principal quantum number,  n

the angular momentum quantum number,  l

and the magnetic quantum number,  m l , can be described like this

l = 0 , 1 , 2 , ... , n − 1  and  m  − l


Now, the d-subshell is described by  

l

=

2

. This mens that any d-subshell you'll ever run into will have a total of five d-orbitals described by

Therefore, the 3d-subshell will contain a total of five 3d-orbitals.

Likewise, the 4d-subshell will contain a total of five 4d-orbitals, the 5d-subshell will contain a total of five 5d-orbitals, and so on.

The important thing to realize here is that there's nothing special about the 3d-subshell in terms of the number of orbitals it contains.

The d-subshell contains five orbitals regardless of the energy level on which the subshell is located - as long as  

n

3

.

Each subshell is characterized by a distinct value of the angular momentum quantum number,  

l

. The number of orbitals each subshell can hold is determined by the magnetic quantum number,  

m

l

.

The relationshop between the principal quantum number,  

n

, the angular momentum quantum number,  

l

, and the magnetic quantum number,  

m

l

, can be described like this

l

=

0

,

1

,

2

,

...

,

n

1

and

m

l

=

l

,

(

l

1

)

,

...

,

1

,

0

,

1

,

...

,

(

l

1

)

,

l

Now, the d-subshell is described by  

l

=

2

. This mens that any d-subshell you'll ever run into will have a total of five d-orbitals described by

m

l

=

{

2

;

1

;

0

;

1

;

2

}

Therefore, the 3d-subshell will contain a total of five 3d-orbitals.

Likewise, the 4d-subshell will contain a total of five 4d-orbitals, the 5d-subshell will contain a total of five 5d-orbitals, and so on.


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