destinguish schottky defect and frenkel defect
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Frenkel Defect:
- Ionic solids containing large differences in the sizes of ions show this type of defect.
- When the smaller ion (usually cation) is dislocated from its normal site to an interstitial site, Frenkel defect is created.
- It creates a vacancy defect as well as an interstitial defect.
- Frenkel defect is also known as dislocation defect.
- Ionic solids such as AgCl, AgBr, AgI, and ZnS show this type of defect.
Schottky defect:
- Schottky defect is basically a vacancy defect shown by ionic solids.
- In this defect, an equal number of cations and anions are missing to maintain electrical neutrality.
- It decreases the density of a substance.
- Significant number of Schottky defects is present in ionic solids.
- For example, in NaCl, there are approximately 106 Schottky pairs per cm3 at room temperature.
- Ionic substances containing similarsized cations and anions show this type of defect.
- For example: NaCl, KCl, CsCl, AgBr, etc.
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