Determine the maximum wavelength that hydrogen in its ground state can absorb. What would be the next smaller wavelength that would work?
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Explanation:
For hydrogen atom, the wavelength :
λ
1
=R(
n
1
2
1
−
n
2
2
1
)
For ground state absorb, n
1
=1
For maximum wavelength, n
2
=2 so 1/λ
max
=R(1/1
2
−1/2
2
)=1.097×10
7
×3/4 or λ
max
=122nm
For next smaller wavelength, n
2
=3 now 1/λ=1.097×10
7
(1−1/9) or λ=103nm
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