determine thermodynamics expression for chemical equilibrium
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The relation K=exp(−ΔrG∘/RT) (Eq. 11.8. 11) gives us a way to evaluate the thermodynamic equilibrium constant K of a reaction at a given temperature from the value of the standard molar reaction Gibbs energy ΔrG∘ at that temperature. If we know the value of ΔrG∘, we can calculate the value of K.
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Equilibrium for any chemical reaction is expressed by an equality ∑νiμi = 0, where μi is the chemical potential of each reagent (i = 1,2, . . .) and νi is the stoichiometric coefficient of each substance in an equation of chemical reaction (it is positive for initial substances and negative for products of a reaction).
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