diamond is bad conductor of electricity but good conductor of heat
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Diamond is a bad conductor of electricity but good conductor of heat. Electricity is conducted in a crystal by electrons that are relatively free. But in diamond, each carbon atom is covalently bonded with four other carbon atoms and there are no free electrons.
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Since the conduction of electricity requires the presence of free electrons, diamond is a bad conductor of electricity. But conduction of heat does not require the presence of free electrons, so diamond is a good conductor of heat
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