Differance between the first stokes and anti stokes transition of a diatomic molecule in ritation raman spectrum is 24cm^1 the separation betweenadjucant lines in pure rotation spectrumof the molecule is
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Vibrational Raman Spectra of Diatomic Molecules. The gross selection rule for the observation of vibrational Raman transitions is that the polarisability of the molecule should change as the molecule vibrates. ... Note that in Raman spectroscopy, the Q branch is always observed.
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