Difference between stauration solubility and intrensic solubility
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The intrinsic solubility is the solubility of the compound in its free acid or free base form. A supersaturated solution is one in which the concentration of dissolved neutral species is greater than the intrinsic solubility. This is not at equilibrium and may or may not have solid precipitate present.
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Unbuffered solubility, usually in water, means solubility of a saturated solution of the compound at the final pH of the solution [1]. ... The intrinsic solubility is the equilibrium solubility of the free acid or base form of an ionizable compound at a pH where it is fully unionized
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