Chemistry, asked by DHRUV7601, 1 year ago

Differences between intermolecular and intramolecular hydrogen bond in ft-ir spectra

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Abstract

The patterns of the NH stretching vibrations in the solid‐state IR spectra of a series of 5‐pyridylmethylenehydantoins revealed the presence of various modes of hydrogen bonding: intermolecular NH&4nldr; &4nldr;OC and intermolecular or intramolecular NH&4nldr; ‥‥N(py). These variations are related to the orientation of the pyridyl nitrogen and to stereochemistry. A distinction between intramolecularly and intermolecularly hydrogen‐bonded compounds was also provided by comparison of the 1H NMR spectra in (CD3)2SO and in CDCl3.

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