Question

Differentiate between aniline and ethylamin

Answer 1

Ethylamine and aniline can be distinguished using the azo-dye test. A dye is obtained when aromatic amines react with at , followed by a reaction with the alkaline solution of 2-naphthol. On the other hand, aniline reacts with at a low temperature to form stable diazonium salt..
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Answer 2

Aniline:

1) Reaction with nitrous acid gives

diazonium salt.

2) Treatment with bromine water,

decolourisation of bromine takes

place with the formation of white

precipitate.

Ethylamine:

1)Reaction with nitrous acid gives

ethyl alcohol.

2) It doesn't form precipitate with

bromine water.