Dimerization of Carboxylic Acids is due to
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Inter molecular hydrogen bonding leads to dimerisation of carboxylic acid in non-aqueous solvent. ...
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Carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen when anhydrous. For example, acetic acid forms a dimer in the gas phase, where the monomer units are held together by hydrogen bonds. Under special conditions, most OH-containing molecules form dimers, e.g. the water dimer.
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