discus fajan s rule and inert pair effect
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Inert pair effect. ... The term "inert pair" was first proposed by Nevil Sidgwick in 1927. The name suggests that the outermost s electrons are more tightly bound to the nucleus in these atoms, and therefore more difficult to ionize or share.
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion.
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» For a given cation, covalent character Increases with increase in size of the anion
» For a given anion, covalent character increases with a decrease in the size of the cation
» Covalent character Increseas with increasing charge either on cation or an anion
» Covalent character is higher for compounds with cations with pseudo noble gas electronic configuration