disscuss the filling of 4f subshell in lanthanides series?
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Lanthanides have the general electron configuration of the type (Xe)4f n 6s2. They're called 4f elements as they have incompletely filled 4f subshells. ... Removal of three electrons is easier from the 4f subshells, so they have a stable oxidation state of +3.
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The lanthanide elements typically have ground state electron configurations of the (Xe)f n s type.
Explanation:
Filling of 4f subshell in lanthanides series:
- lanthanum is not included in this generalization, it is listed in the table due to other similarities and its uniform trivalency. Three lanthanides exhibit deviations from the typical f n d0 s pattern.
- When compared to f d, Cerium's increase in effective nuclear charge following Lanthanum is insufficient to stabilize the f d0 configuration. The f orbitals' energy cannot be contracted to levels well below the d by the nuclear charge.
- The fd1 configuration of gadolinium is in line with what we would anticipate from a stabilized half-filled f shell.
- Additionally, lutetium has the f d configuration, in which the final electron is added in excess of what the f shell can accommodate.
Note: The table you're looking at on provides the Lanthanides' ground state electron configurations.
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