Distinguish between chain growth and step growth
polymer.
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Step-Growth
- All molecules present (monomer, oligomer, polymer) can react with any other molecule.
- Monomers exist throughout the reaction, but large quantities of monomers are consumed early in the reaction.
Chain-Growth
- During propagation, only monomers react to the “active site” at the end of the growing chain.
- Monomers exist throughout the reaction; its concentration decreases steadily with time.
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