DL configuration based on
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molecule glyceraldehyde
Background of D/L notation
Background of D/L notationThe d/l system (named after Latin dexter and laevus, right and left) names molecules by relating them to the molecule glyceraldehyde. Glyceraldehyde is chiral, and its two isomers are labeled d and l (typically typeset in small caps in published work).
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The D-L system corresponds to the configuration of the molecule: spatial arrangement of its atoms around the chirality center. ... (D-L system labels the whole molecule, while R/S system labels the absolute configuration of each chirality center.) In short, the D-L system doesn't have direct connection to (+)/(-) notation.
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