Question

Do aryl halides undergo nucleophilic substitution

Answer 1

Answer:

Substitution reaction

Aryl halides are relatively unreactive toward nucleophilic substitution reactions. ... First, the carbon atom in aryl halides is sp 2 hybridized instead of sp 3 hybridized as in alkyl halides. Second, the carbon‐halogen bond has partial double bond characteristics because of resonance.

Answer 2

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ANSWER :

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Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to resonance stabilization.

Due to resonance, C−Cl bond acquires partial double bond character and becomes shorter and stronger and cannot be easily replaced by nucleophiles. 

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