Do aryl halides undergo nucleophilic substitution
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Substitution reaction
Aryl halides are relatively unreactive toward nucleophilic substitution reactions. ... First, the carbon atom in aryl halides is sp 2 hybridized instead of sp 3 hybridized as in alkyl halides. Second, the carbon‐halogen bond has partial double bond characteristics because of resonance.
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Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to resonance stabilization.
Due to resonance, C−Cl bond acquires partial double bond character and becomes shorter and stronger and cannot be easily replaced by nucleophiles.
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