Do state law of equipartition of energy .use this law to calculate specific heats of monoatomi diatomic triatomic gases
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According to the law of equipartition of energy, the energy is equally distributed among all the degrees of freedom and that is equal to 1/2 kT. Therefore, if the degrees of freedom of gas molecules are f then internal energy of 1 mole of gas will be
, where N is the Avogadro number.
Atomicity
Degrees of freedom
U
Monoatomic gas
3
begin mathsize 12px style 3 over 2 kT end style
Diatomic gas
5
begin mathsize 12px style 5 over 2 kT end style
Angular triatomic gas
6
begin mathsize 12px style 6 over 2 kT end style
Linear triatomic gas
7
begin mathsize 12px style 7 over 2 kT end style
, where N is the Avogadro number.
Atomicity
Degrees of freedom
U
Monoatomic gas
3
begin mathsize 12px style 3 over 2 kT end style
Diatomic gas
5
begin mathsize 12px style 5 over 2 kT end style
Angular triatomic gas
6
begin mathsize 12px style 6 over 2 kT end style
Linear triatomic gas
7
begin mathsize 12px style 7 over 2 kT end style
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