Do the convention
Benzene to m- Dichloro benzene
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STEP 1: NITRATION
C6H6 + NO2 ----> C6H5(NO2)
STEP 2: CHLORINATION
C6H5(NO2) + Cl ----> C6H4(NO2)(Cl) [1-chloro-3-nitrobenzene]
You can reduce the nitro group to an amino group and then proceed with the Sandmeyer reaction.
C6H4(NO2)Cl ----Fe+HCl-----> C6H4(NH2)Cl
After sandmeyer's reaction: C6H4Cl2 (1,3-Dichlorobenzene)
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