Chemistry, asked by saurabhwagh5097, 1 month ago

Draw resonance structure showing +R effect in aniline and -R effect in Nitrobenzene.

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Answered by riyaa22131

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The molecular orbitals of aniline (calculated at DF-BP86-D3BJ/def2-SVP; Gaussian 09 D.01) show that the nitrogen is part of the π-system. They are also very similar to benzene. Here are the orbitals of the π-system in decreasing energy. Virtual (unoccupied) orbitals are red/yellow, and occupied orbitals are blue/orange.

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