(e) By reaction of HNO, on Aliphatic Primary Amine
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The reaction of aromatic primary amines with nitrous acid gives aromatic diazonium salts.
The reaction of aliphatic primary amines with nitrous acid gives aromatic diazonium salts which decompose to form a mixture of compounds containing alkyl chlorides, alkenes and alcohols. Usually, alcohols are the major products. The reactions are shown above.
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