energy of 1s orbital of He is greater than H??
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You fell into a wrong analogy with the picture of energetically far apart. Let me break down your picture into something visible:
Imagine the orbitals of fluorine at different heights of a mountain (I’ll use the Zugspitze, because it feels like home). 1s is at the very peak of the mountain (yeah, I’m turning this around just for simplicity). The Eibsee (c. 1000 m1000 m over sea level) would correspond to the 2s-orbital. Garmisch-Partenkirchen, the town in the valley before the mountain, (700 m700 m) would be the 2p orbital.
We need to place the 1s-orbital of hydrogen somewhere so that the height difference to the Eibsee is too large for an interaction. One possibility would be the Höllentalanger hut at around 1300 m1300 m. That would render the energy difference to both fluorine’s 2s and 2p too large. But in fact, hydrogen’s 1s is better placed at the height of Oberau, 650 m650 m. That is way too far away from the 2s but rather close to the 2p.
This is confirmed by energy diagrams of HFHF like that presented in this lecture (in German). (Just search for HF on the page, it’s not far down. Ignore the text around it and look at the scheme.)
Imagine the orbitals of fluorine at different heights of a mountain (I’ll use the Zugspitze, because it feels like home). 1s is at the very peak of the mountain (yeah, I’m turning this around just for simplicity). The Eibsee (c. 1000 m1000 m over sea level) would correspond to the 2s-orbital. Garmisch-Partenkirchen, the town in the valley before the mountain, (700 m700 m) would be the 2p orbital.
We need to place the 1s-orbital of hydrogen somewhere so that the height difference to the Eibsee is too large for an interaction. One possibility would be the Höllentalanger hut at around 1300 m1300 m. That would render the energy difference to both fluorine’s 2s and 2p too large. But in fact, hydrogen’s 1s is better placed at the height of Oberau, 650 m650 m. That is way too far away from the 2s but rather close to the 2p.
This is confirmed by energy diagrams of HFHF like that presented in this lecture (in German). (Just search for HF on the page, it’s not far down. Ignore the text around it and look at the scheme.)
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