Chemistry, asked by dilipkumar713343, 7 months ago

energy of electronin orbit of H atom is -1.51eV.Wavelength produced by the electron in same orbit if first orbit of H have radius 1)2pie *x 2)3pie*x 3)6pie*x 4)9pie*x​

Answers

Answered by premsaiguntur357
0

Answer:

Explanation:

The key to this problem lies with what characterizes a radial node.

Basically, the wave function,

Ψ

(

x

)

, is simply a mathematical function used to describe a quantum object.

The wave function that describes an electron in an atom is actually a product between the radial wave function, which is of interest in your case, and the angular wave function.

The radial wave function depends only on the distance from the nucleus,

r

.

Now, a node occurs when a wave function changes signs, i.e. when its passes through zero. A radial node occurs when a radial wave function passes through zero.

The important thing to remember about nodes is that an electron has zero probability of being located at a node. The probability of an electron being located at a particular point is given by the square of the absolute value of the wave function,

|

Ψ

(

x

)

|

2

.

Since you have zero probability of locating an electron at a node, you can say that you have

|

Ψ

(

x

)

|

2

=

0

this is true at nodes

So, you are given the wave function of a 2s-orbital

Ψ

2

s

=

1

2

2

π

1

a

0

(

2

r

a

0

)

e

r

2

a

0

and told that at

r

=

r

0

, a radial node is formed. Right from the start, this tells you that you have

|

Ψ

2

s

|

2

=

0

Now, take a look at the wave function again. The only way to get the square of its absolute value equal to zero is if you have

(

2

r

a

0

)

=

0

since

Ψ

2

s

=

>

0



1

2

2

π

1

a

0

(

2

r

a

0

)

>

0



e

r

2

a

0

This means that you have

2

r

a

0

=

0

r

=

2

a

0

At

r

=

r

0

, you will have

r

0

=

2

a

0

Here's how the wave function for the 2s-orbital looks

A 2s-orbital is characterized by the fact that it has no directional properties - you get the exact same value for its wave function regardless of the value of

r

This is why the 2s-orbital is spherical in shape.

Moreover, this tells you that the wave function changes signs at the same distance from the nucleus in all directions, which is why a nodal surface is formed.

The wave function of a 2s-orbital changes signs once, so you only have one nodal surface here.

Answered by nagarjunachinni
2

Answer:Radius of 3rd orbit = r = R(3)^2

= 9 R

[Here R = Radius of first orbit of hydrogen atom]

mvr = nh / (2 π)

h/(mv) = 2πr / n

λ = h / (mv) = 2π × 9R / 3

λ = 6πR

λ = 6 π × (0.529 Å)

λ = 9.97 Å

De-Broglie wavelength is 9.97 Å

Explanation:

Please mark it as THE BRAINLIEST ANSWER!

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