Enthalpy of sublimation of a substance is equal to
(a) enthalpy of fusion + enthalpy of vapourisation
(b) enthalpy of fusion
(c) enthalpy of vapourisation
(d) twice the enthalpy of vapourisation.
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Explanation:
(a) Enthalpy of sublimation of a substance is equal to enthalpy of fusion + enthalpy of vapourisation.
Sublimation is direct conversion of solid to vapour, i.e., solid → vapour
Writing in two steps, we have solid → liquid → vapour.
Solid → liquid requires enthalpy of fusion.
Liquid →vapour requires enthalpy of vapourisation
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