Equal weights of carbon and oxygen are heated in a closed vessel producing CO and CO2 in a 1: 1 mol ratio. Find which component is limiting and which component left and what is its percentage out of total weight taken?
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Answer:
Let, 1 mole of each of
P
2
O
5
and
P
2
O
3
is formed. So the mole ratio of the reacting P and O atoms is 4:8 or 1:2
Let the mass of oxygen and phosphorus atoms be
W
.
Therfore, moles of oxygen atoms =
W
16
moles of phosphorus atoms =
W
31
From the mole ratio,
2 moles of oxygen atoms combine with 1 mole of phosphorus atoms.
∴
W
16
moles of oxygen atoms combine with
W
32
moles of phosphorus atoms.
So here phosphorus is the excess component.
So, moles of phosphorus remaining
=
W
31
−
W
32
Hence mole parcentage of the excess component
=
(
W
31
−
W
32
)
W
31
×
100
=
1
32
×
100
=
3.125
%
Explanation:
Hope it helps u
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