equation for conversion of aniline into 4bromo aniline
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Aniline reacts with Pyridine to give Phenylethanamide (CH3CO)2O. It further reacts with Bromine (Br2) in the presence of acetic acid (CH3COOH) to give Bromoacetanilide (it is the major product in the reaction). It can further react with either Hydrogen ion or Hydroxyl ion to give Bromoaniline.
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In order to carry out mono bromination you should reduce the activating effect of amino group by acetylation and then bromination is carried out.
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