Equivalent mass for disproportionation reaction
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We all know that Equivalent weight=Molecular weightn-factor However consider a reaction like: BrX2+OHX−⟶BrX−+BrOX3X−+HX2O where oxidation numbers ..
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So for oxidation, electron exchange=2*5=10. Dividing by total number of bromine molecules, i.e. 6, the Valency Factor of bromine molecule in the above disproportionation reaction is 10/6. If we look only reduction, then total electron exchange= 10*1=10.
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