establish a relation between entropy and the thermodynamic probability
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follows therefore that if the thermodynamic probability W of a system increases, its entropy S must increase too. Further, since W always increases in a spontaneous change, it follows that S must also increase in such a change.
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Entropy
- The information encapsulated by entropy is information about the underlying probability distribution, not the significance of the events themselves, because it only considers the likelihood of detecting a single occurrence.
Thermodynamic probability
- When a system's thermodynamic probability W grows, its entropy S must also increase. Furthermore, because W always grows in a spontaneous change, S must likewise increase in the same change.
- The thermodynamic probability is represented as a whole number, which is usually quite big.
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